TY  - JOUR
A1  - Abbas, Karim
A1  - Balc, Nicolae
A1  - Bremen, Sebastian
A1  - Skupin, Marco
T1  - Crystallization and aging behavior of polyetheretherketone PEEK within rapid tooling and rubber molding
T2  - Journal of Manufacturing and Materials Processing
N2  - In times of short product life cycles, additive manufacturing and rapid tooling are important methods to make tool development and manufacturing more efficient. High-performance polymers are the key to mold production for prototypes and small series. However, the high temperatures during vulcanization injection molding cause thermal aging and can impair service life. The extent to which the thermal stress over the entire process chain stresses the material and whether it leads to irreversible material aging is evaluated. To this end, a mold made of PEEK is fabricated using fused filament fabrication and examined for its potential application. The mold is heated to 200 ◦C, filled with rubber, and cured. A differential scanning calorimetry analysis of each process step illustrates the crystallization behavior and first indicates the material resistance. It shows distinct cold crystallization regions at a build chamber temperature of 90 ◦C. At an ambient temperature above Tg, crystallization of 30% is achieved, and cold crystallization no longer occurs. Additional tensile tests show a decrease in tensile strength after ten days of thermal aging. The steady decrease in recrystallization temperature indicates degradation of the additives. However, the tensile tests reveal steady embrittlement of the material due to increasing crosslinking.
KW  - additive manufacturing
KW  - fused filament fabrication
KW  - crystallization
KW  - polyetheretherketone
KW  - rapid tooling
Y1  - 2022
UR  - https://opus.bibliothek.fh-aachen.de/opus4/frontdoor/index/index/docId/10177
SN  - 2504-4494
N1  - The article belongs to the Special Issue Advances in Injection Molding: Process, Materials and Applications
VL  - 6
IS  - 5
SP  - 1
EP  - 12
PB  - MDPI
CY  - Basel
ER  -