@inproceedings{SakthivelWeppner2006, author = {Sakthivel, Mariappan and Weppner, Werner}, title = {Response behaviour of a hydrogen sensor based on ionic conducting polymer-metal interfaces prepared by the chemical reduction method}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:a96-opus-1399}, year = {2006}, abstract = {A solid-state amperometric hydrogen sensor based on a protonated Nafion membrane and catalytic active electrode operating at room temperature was fabricated and tested. Ionic conducting polymer-metal electrode interfaces were prepared chemically by using the impregnation-reduction method. The polymer membrane was impregnated with tetra-ammine platinum chloride hydrate and the metal ions were subsequently reduced by using either sodium tetrahydroborate or potassium tetrahydroborate. The hydrogen sensing characteristics with air as reference gas is reported. The sensors were capable of detecting hydrogen concentrations from 10 ppm to 10\% in nitrogen. The response time was in the range of 10-30 s and a stable linear current output was observed. The thin Pt films were characterized by XRD, Infrared Spectroscopy, Optical Microscopy, Atomic Force Microscopy, Scanning Electron Microscopy and EDAX.}, subject = {Biosensor}, language = {en} } @inproceedings{BarekFischerNavratiletal.2006, author = {Barek, Jiri and Fischer, Jan and Navratil, Tomas and Peckova, Karolina and Yosypchuk, Bogdan}, title = {Silver solid amalgam electrodes as sensors for chemical carcinogens}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:a96-opus-1554}, year = {2006}, abstract = {The applicability of differential pulse voltammetry (DPV) and adsorptive stripping voltammetry (AdSV) at a non-toxic meniscus-modified silver solid amalgam electrode (m-AgSAE) for the determination of trace amounts of genotoxic substances was demonstrated on the determination of micromolar and submicromolar concentrations of 3-nitrofluoranthene using methanol - 0.01 mol L-1 NaOH (9:1) mixture as a base electrolyte and of Ostazine Orange using 0.01 mol L-1 NaOH as a base electrolyte.}, subject = {Biosensor}, language = {en} } @inproceedings{SrivastavaSinghDhandetal.2006, author = {Srivastava, Alok and Singh, Virendra and Dhand, Chetna and Kaur, Manindar and Singh, Tejvir and Witte, Katrin and Scherer, Ulrich W.}, title = {Study of swift heavy ion modified conduction polymer composites for application as gas sensor}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:a96-opus-1345}, year = {2006}, abstract = {A polyaniline-based conducting composite was prepared by oxidative polymerisation of aniline in a polyvinylchloride (PVC) matrix. The coherent free standing thin films of the composite were prepared by a solution casting method. The polyvinyl chloride-polyaniline composites exposed to 120 MeV ions of silicon with total ion fluence ranging from 1011 to 1013 ions/cm2, were observed to be more sensitive towards ammonia gas than the unirradiated composite. The response time of the irradiated composites was observed to be comparably shorter. We report for the first time the application of swift heavy ion modified insulating polymer conducting polymer (IPCP) composites for sensing of ammonia gas.}, subject = {Biosensor}, language = {en} } @inproceedings{PijanowskaRemiszewskaPederzollietal.2006, author = {Pijanowska, Dorota G. and Remiszewska, Elzbieta and Pederzolli, Cecilia and Lunelli, Lorenzo and Vendano, Michele and Canteri, Roberto and Dudzinski, Konrad and Kruk, Jerzy and Torbicz, Wladyslaw}, title = {Surface modification for microreactor fabrication}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:a96-opus-1480}, year = {2006}, abstract = {In this paper, methods of surface modification of different supports, i.e. glass and polymeric beads for enzyme immobilisation are described. The developed method of enzyme immobilisation is based on Schiff's base formation between the amino groups on the enzyme surface and the aldehyde groups on the chemically modified surface of the supports. The surface of silicon modified by APTS and GOPS with immobilised enzyme was characterised by atomic force microscopy (AFM), time-of-flight secondary ion mass spectroscopy (ToF-SIMS) and infrared spectroscopy (FTIR). The supports with immobilised enzyme (urease) were also tested in combination with microreactors fabricated in silicon and Perspex, operating in a flow-through system. For microreactors filled with urease immobilised on glass beads (Sigma) and on polymeric beads (PAN), a very high and stable signal (pH change) was obtained. The developed method of urease immobilisation can be stated to be very effective.}, subject = {Biosensor}, language = {en} } @inproceedings{KoplinSiemonsOcenValentinetal.2006, author = {Koplin, Tobias J. and Siemons, Maike and Oc{\´e}n-Val{\´e}ntin, C{\´e}sar and Sanders, Daniel and Simon, Ulrich}, title = {Workflow for high throughput screening of gas sensing materials}, url = {http://nbn-resolving.de/urn:nbn:de:hbz:a96-opus-1407}, year = {2006}, abstract = {The workflow of a high throughput screening setup for the rapid identification of new and improved sensor materials is presented. The polyol method was applied to prepare nanoparticular metal oxides as base materials, which were functionalised by surface doping. Using multi-electrode substrates and high throughput impedance spectroscopy (HT-IS) a wide range of materials could be screened in a short time. Applying HT-IS in search of new selective gas sensing materials a NO2-tolerant NO sensing material with reduced sensitivities towards other test gases was identified based on iridium doped zinc oxide. Analogous behaviour was observed for iridium doped indium oxide.}, subject = {Biosensor}, language = {en} }