@article{MiyamotoBingWagneretal.2015, author = {Miyamoto, Ko-ichiro and Bing, Yu and Wagner, Torsten and Yoshinobu, Tatsuo and Sch{\"o}ning, Michael Josef}, title = {Visualization of Defects on a Cultured Cell Layer by Utilizing Chemical Imaging Sensor}, series = {Procedia Engineering}, volume = {120}, journal = {Procedia Engineering}, publisher = {Elsevier}, address = {Amsterdam}, issn = {1877-7058}, doi = {10.1016/j.proeng.2015.08.806}, pages = {936 -- 939}, year = {2015}, abstract = {The chemical imaging sensor is a field-effect sensor which is able to visualize both the distribution of ions (in LAPS mode) and the distribution of impedance (in SPIM mode) inthe sample. In this study, a novel wound-healing assay is proposed, in which the chemical imaging sensor operated in SPIM mode is applied to monitor the defect of a cell layer brought into proximity of the sensing surface.A reduced impedance inside the defect, which was artificially formed ina cell layer, was successfully visualized in a photocurrent image.}, language = {en} } @article{WindmuellerSchapsZantisetal.2024, author = {Windm{\"u}ller, Anna and Schaps, Kristian and Zantis, Frederik and Domgans, Anna and Taklu, Bereket Woldegbreal and Yang, Tingting and Tsai, Chih-Long and Schierholz, Roland and Yu, Shicheng and Kungl, Hans and Tempel, Hermann and Dunin-Borkowski, Rafal E. and H{\"u}ning, Felix and Hwang, Bing Joe and Eichel, R{\"u}diger-A.}, title = {Electrochemical activation of LiGaO2: implications for ga-doped garnet solid electrolytes in li-metal batteries}, series = {ACS Applied Materials \& Interfaces}, volume = {16}, journal = {ACS Applied Materials \& Interfaces}, number = {30}, publisher = {ACS Publications}, address = {Washington, DC}, issn = {39181-3919}, doi = {10.1021/acsami.4c03729}, pages = {14 Seiten}, year = {2024}, abstract = {Ga-doped Li7La3Zr2O12 garnet solid electrolytes exhibit the highest Li-ion conductivities among the oxide-type garnet-structured solid electrolytes, but instabilities toward Li metal hamper their practical application. The instabilities have been assigned to direct chemical reactions between LiGaO2 coexisting phases and Li metal by several groups previously. Yet, the understanding of the role of LiGaO2 in the electrochemical cell and its electrochemical properties is still lacking. Here, we are investigating the electrochemical properties of LiGaO2 through electrochemical tests in galvanostatic cells versus Li metal and complementary ex situ studies via confocal Raman microscopy, quantitative phase analysis based on powder X-ray diffraction, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and electron energy loss spectroscopy. The results demonstrate considerable and surprising electrochemical activity, with high reversibility. A three-stage reaction mechanism is derived, including reversible electrochemical reactions that lead to the formation of highly electronically conducting products. The results have considerable implications for the use of Ga-doped Li7La3Zr2O12 electrolytes in all-solid-state Li-metal battery applications and raise the need for advanced materials engineering to realize Ga-doped Li7La3Zr2O12for practical use.}, language = {en} }