TY - JOUR A1 - Windmüller, Anna A1 - Schaps, Kristian A1 - Zantis, Frederik A1 - Domgans, Anna A1 - Taklu, Bereket Woldegbreal A1 - Yang, Tingting A1 - Tsai, Chih-Long A1 - Schierholz, Roland A1 - Yu, Shicheng A1 - Kungl, Hans A1 - Tempel, Hermann A1 - Dunin-Borkowski, Rafal E. A1 - Hüning, Felix A1 - Hwang, Bing Joe A1 - Eichel, Rüdiger-A. T1 - Electrochemical activation of LiGaO2: implications for ga-doped garnet solid electrolytes in li-metal batteries JF - ACS Applied Materials & Interfaces N2 - Ga-doped Li7La3Zr2O12 garnet solid electrolytes exhibit the highest Li-ion conductivities among the oxide-type garnet-structured solid electrolytes, but instabilities toward Li metal hamper their practical application. The instabilities have been assigned to direct chemical reactions between LiGaO2 coexisting phases and Li metal by several groups previously. Yet, the understanding of the role of LiGaO2 in the electrochemical cell and its electrochemical properties is still lacking. Here, we are investigating the electrochemical properties of LiGaO2 through electrochemical tests in galvanostatic cells versus Li metal and complementary ex situ studies via confocal Raman microscopy, quantitative phase analysis based on powder X-ray diffraction, energy-dispersive X-ray spectroscopy, X-ray photoelectron spectroscopy, and electron energy loss spectroscopy. The results demonstrate considerable and surprising electrochemical activity, with high reversibility. A three-stage reaction mechanism is derived, including reversible electrochemical reactions that lead to the formation of highly electronically conducting products. The results have considerable implications for the use of Ga-doped Li7La3Zr2O12 electrolytes in all-solid-state Li-metal battery applications and raise the need for advanced materials engineering to realize Ga-doped Li7La3Zr2O12for practical use. KW - LiGaO2 KW - garnet solid electrolyte KW - ga-doping KW - Li7La3Zr2O12 KW - solid-state battery Y1 - 2024 U6 - https://doi.org/10.1021/acsami.4c03729 SN - 39181–3919 VL - 16 IS - 30 PB - ACS Publications CY - Washington, DC ER - TY - BOOK A1 - Winkler, Norbert T1 - Zahlentafeln für den Baubetrieb / Hoffmann, Manfred [Hrsg.]. 6., vollst. aktualisierte Aufl. ... Norbert Winkler [Bearb.] Y1 - 2002 SN - 3-519-55220-5 PB - Teubner CY - Stuttgart [u.a.] ER - TY - JOUR A1 - Winkler, Norbert T1 - Vermessung zur Bauzeit der Zitadelle und heute : Bastion Wilhelmus / von Norbert Winkler JF - 4 Bastionen, 4 Aspekte : aktuelle Arbeiten zur Zitadelle Jülich ; Katalog zur Ausstellung im Hexenturm 10.11.95 - 14.02.96 / [Veranst.: Stadtgeschichtliches Museum Jülich]. Mit Beitr. von Guido von Büren ... [Hrsg.: Marcell Perse] Y1 - 1995 N1 - Führer des Stadtgeschichtlichen Museums Jülich ; 7 SP - 77 EP - 115 CY - Jülich ER - TY - JOUR A1 - Winkler, Norbert T1 - Vermessung JF - Zahlentafeln für den Baubetrieb / Hoffmann, Manfred ; Kuhlmann, Willy [Hrsg.]. 7., vollst. überarb. Aufl. Y1 - 2006 SN - 3-519-65220-X N1 - Kapitel 3 SP - 147 EP - 160 PB - Teubner CY - Wiesbaden ER - TY - JOUR A1 - Winkler, Norbert T1 - Vermessung JF - Beispiele für die Baubetriebspraxis / Hoffmann, Manfred ; Kuhlmann, Willy [Hrsg.]. Y1 - 2006 SN - 978-3-8351-0002-2 N1 - Kapitel 2 SP - 9 EP - 34 PB - Teubner CY - Wiesbaden ER - TY - CHAP A1 - Winkler, Norbert T1 - Vermessung T2 - Zahlentafeln für den Baubetrieb Y1 - 2016 SN - 978-3-658-02838-1 (Online) SN - 978-3-658-02837-4 (Print) U6 - https://doi.org/10.1007/978-3-658-02838-1_3 SP - 159 EP - 177 PB - Springer Vieweg CY - Wiesbaden ET - 9., überarb. und aktual. Aufl. ER - TY - JOUR A1 - Wissen, M. A1 - Bogdanski, N. A1 - Scheer, H.-C. A1 - Bitz, Andreas A1 - Ahrens, G. A1 - Gruetzner, G. T1 - Implication of the light polarisation for UV curing of pre-patterned resists JF - Microelectronic Engineering Y1 - 2005 U6 - https://doi.org/10.1016/j.mee.2004.12.099 SN - 0167-9317 VL - 78-79 SP - 659 EP - 664 ER - TY - JOUR A1 - Wissenbach, U. A1 - Six, S. A1 - Bongaerts, Johannes A1 - Ternes, D. A1 - Steinwachs, S. A1 - Unden, G. T1 - A third periplasmic transport system for l-arginine in Escherichia coli: molecular characterization of the artPIQMJ genes, arginine binding and transport JF - Molecular microbiology Y1 - 1995 SN - 1365-2958 (E-Journal); 0950-382x (Print) VL - Vol. 17 IS - Iss. 4 SP - 675 EP - 686 ER - TY - JOUR A1 - Witt, Klaus A1 - Bogner, D. T1 - Druckmessung mit zukunftsorientierten Perspektiven JF - Sensor Report. 5 (1990), H. 1 Y1 - 1990 SN - 0179-9592 SP - 8 EP - 14 ER - TY - BOOK A1 - Witte, Bertold A1 - Sparla, Peter T1 - Vermessungskunde und Grundlagen der Statistik für das Bauwesen Y1 - 2011 SN - 978-3-87907-497-6 PB - Wichmann CY - Heidelberg ET - 7., überarb. erw. Aufl. ER -