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Frequency mixing magnetic detection (FMMD) is a sensitive and selective technique to detect magnetic nanoparticles (MNPs) serving as probes for binding biological targets. Its principle relies on the nonlinear magnetic relaxation dynamics of a particle ensemble interacting with a dual frequency external magnetic field. In order to increase its sensitivity, lower its limit of detection and overall improve its applicability in biosensing, matching combinations of external field parameters and internal particle properties are being sought to advance FMMD. In this study, we systematically probe the aforementioned interaction with coupled Néel–Brownian dynamic relaxation simulations to examine how key MNP properties as well as applied field parameters affect the frequency mixing signal generation. It is found that the core size of MNPs dominates their nonlinear magnetic response, with the strongest contributions from the largest particles. The drive field amplitude dominates the shape of the field-dependent response, whereas effective anisotropy and hydrodynamic size of the particles only weakly influence the signal generation in FMMD. For tailoring the MNP properties and parameters of the setup towards optimal FMMD signal generation, our findings suggest choosing large particles of core sizes dc > 25 nm nm with narrow size distributions (σ < 0.1) to minimize the required drive field amplitude. This allows potential improvements of FMMD as a stand-alone application, as well as advances in magnetic particle imaging, hyperthermia and magnetic immunoassays.
Technical assessment of Brayton cycle heat pumps for the integration in hybrid PV-CSP power plants
(2022)
The hybridization of Concentrated Solar Power (CSP) and Photovoltaics (PV) systems is a promising approach to reduce costs of solar power plants, while increasing dispatchability and flexibility of power generation. High temperature heat pumps (HT HP) can be utilized to boost the salt temperature in the thermal energy storage (TES) of a Parabolic Trough Collector (PTC) system from 385 °C up to 565 °C. A PV field can supply the power for the HT HP, thus effectively storing the PV power as thermal energy. Besides cost-efficiently storing energy from the PV field, the power block efficiency of the overall system is improved due to the higher steam parameters. This paper presents a technical assessment of Brayton cycle heat pumps to be integrated in hybrid PV-CSP power plants. As a first step, a theoretical analysis was carried out to find the most suitable working fluid. The analysis included the fluids Air, Argon (Ar), Nitrogen (N2) and Carbon dioxide (CO2). N2 has been chosen as the optimal working fluid for the system. After the selection of the ideal working medium, different concepts for the arrangement of a HT HP in a PV-CSP hybrid power plant were developed and simulated in EBSILON®Professional. The concepts were evaluated technically by comparing the number of components required, pressure losses and coefficient of performance (COP).
In the past, CSP and PV have been seen as competing technologies. Despite massive reductions in the electricity generation costs of CSP plants, PV power generation is - at least during sunshine hours - significantly cheaper. If electricity is required not only during the daytime, but around the clock, CSP with its inherent thermal energy storage gets an advantage in terms of LEC. There are a few examples of projects in which CSP plants and PV plants have been co-located, meaning that they feed into the same grid connection point and ideally optimize their operation strategy to yield an overall benefit. In the past eight years, TSK Flagsol has developed a plant concept, which merges both solar technologies into one highly Integrated CSP-PV-Hybrid (ICPH) power plant. Here, unlike in simply co-located concepts, as analyzed e.g. in [1] – [4], excess PV power that would have to be dumped is used in electric molten salt heaters to increase the storage temperature, improving storage and conversion efficiency. The authors demonstrate the electricity cost sensitivity to subsystem sizing for various market scenarios, and compare the resulting optimized ICPH plants with co-located hybrid plants. Independent of the three feed-in tariffs that have been assumed, the ICPH plant shows an electricity cost advantage of almost 20% while maintaining a high degree of flexibility in power dispatch as it is characteristic for CSP power plants. As all components of such an innovative concept are well proven, the system is ready for commercial market implementation. A first project is already contracted and in early engineering execution.
In order to realistically predict and optimize the actual performance of a concentrating solar power (CSP) plant sophisticated simulation models and methods are required. This paper presents a detailed dynamic simulation model for a Molten Salt Solar Tower (MST) system, which is capable of simulating transient operation including detailed startup and shutdown procedures including drainage and refill. For appropriate representation of the transient behavior of the receiver as well as replication of local bulk and surface temperatures a discretized receiver model based on a novel homogeneous two-phase (2P) flow modelling approach is implemented in Modelica Dymola®. This allows for reasonable representation of the very different hydraulic and thermal properties of molten salt versus air as well as the transition between both. This dynamic 2P receiver model is embedded in a comprehensive one-dimensional model of a commercial scale MST system and coupled with a transient receiver flux density distribution from raytracing based heliostat field simulation. This enables for detailed process prediction with reasonable computational effort, while providing data such as local salt film and wall temperatures, realistic control behavior as well as net performance of the overall system. Besides a model description, this paper presents some results of a validation as well as the simulation of a complete startup procedure. Finally, a study on numerical simulation performance and grid dependencies is presented and discussed.
Despite the challenges of pioneering molten salt towers (MST), it remains the leading technology in central receiver power plants today, thanks to cost effective storage integration and high cost reduction potential. The limited controllability in volatile solar conditions can cause significant losses, which are difficult to estimate without comprehensive modeling [1]. This paper presents a Methodology to generate predictions of the dynamic behavior of the receiver system as part of an operating assistance system (OAS). Based on this, it delivers proposals if and when to drain and refill the receiver during a cloudy period in order maximize the net yield and quantifies the amount of net electricity gained by this. After prior analysis with a detailed dynamic two-phase model of the entire receiver system, two different reduced modeling approaches where developed and implemented in the OAS. A tailored decision algorithm utilizes both models to deliver the desired predictions efficiently and with appropriate accuracy.
The integration of high temperature thermal energy storages into existing conventional power plants can help to reduce the CO2 emissions of those plants and lead to lower capital expenditures for building energy storage systems, due to the use of synergy effects [1]. One possibility to implement that, is a molten salt storage system with a powerful power-to-heat unit. This paper presents two possible control concepts for the startup of the charging system of such a facility. The procedures are implemented in a detailed dynamic process model. The performance and safety regarding the film temperatures at heat transmitting surfaces are investigated in the process simulations. To improve the accuracy in predicting the film temperatures, CFD simulations of the electrical heater are carried out and the results are merged with the dynamic model. The results show that both investigated control concepts are safe regarding the temperature limits. The gradient controlled startup performed better than the temperature-controlled startup. Nevertheless, there are several uncertainties that need to be investigated further.
Residential and commercial buildings account for more than one-third of global energy-related greenhouse gas emissions. Integrated multi-energy systems at the district level are a promising way to reduce greenhouse gas emissions by exploiting economies of scale and synergies between energy sources. Planning district energy systems comes with many challenges in an ever-changing environment. Computational modelling established itself as the state-of-the-art method for district energy system planning. Unfortunately, it is still cumbersome to combine standalone models to generate insights that surpass their original purpose. Ideally, planning processes could be solved by using modular tools that easily incorporate the variety of competing and complementing computational models. Our contribution is a vision for a collaborative development and application platform for multi-energy system planning tools at the district level. We present challenges of district energy system planning identified in the literature and evaluate whether this platform can help to overcome these challenges. Further, we propose a toolkit that represents the core technical elements of the platform. Lastly, we discuss community management and its relevance for the success of projects with collaboration and knowledge sharing at their core.
Analyzing electroencephalographic (EEG) time series can be challenging, especially with deep neural networks, due to the large variability among human subjects and often small datasets. To address these challenges, various strategies, such as self-supervised learning, have been suggested, but they typically rely on extensive empirical datasets. Inspired by recent advances in computer vision, we propose a pretraining task termed "frequency pretraining" to pretrain a neural network for sleep staging by predicting the frequency content of randomly generated synthetic time series. Our experiments demonstrate that our method surpasses fully supervised learning in scenarios with limited data and few subjects, and matches its performance in regimes with many subjects. Furthermore, our results underline the relevance of frequency information for sleep stage scoring, while also demonstrating that deep neural networks utilize information beyond frequencies to enhance sleep staging performance, which is consistent with previous research. We anticipate that our approach will be advantageous across a broad spectrum of applications where EEG data is limited or derived from a small number of subjects, including the domain of brain-computer interfaces.
A promising approach to reduce the system costs of molten salt solar receivers is to enable the irradiation of the absorber tubes on both sides. The star design is an innovative receiver design, pursuing this approach. The unconventional design leads to new challenges in controlling the system. This paper presents a control concept for a molten salt receiver system in star design. The control parameters are optimized in a defined test cycle by minimizing a cost function. The control concept is tested in realistic cloud passage scenarios based on real weather data. During these tests, the control system showed no sign of unstable behavior, but to perform sufficiently in every scenario further research and development like integrating Model Predictive Controls (MPCs) need to be done. The presented concept is a starting point to do so.
Concerning current efforts to improve operational efficiency and to lower overall costs of concentrating solar power (CSP) plants with prediction-based algorithms, this study investigates the quality and uncertainty of nowcasting data regarding the implications for process predictions. DNI (direct normal irradiation) maps from an all-sky imager-based nowcasting system are applied to a dynamic prediction model coupled with ray tracing. The results underline the need for high-resolution DNI maps in order to predict net yield and receiver outlet temperature realistically. Furthermore, based on a statistical uncertainty analysis, a correlation is developed, which allows for predicting the uncertainty of the net power prediction based on the corresponding DNI forecast uncertainty. However, the study reveals significant prediction errors and the demand for further improvement in the accuracy at which local shadings are forecasted.