Article
Refine
Year of publication
- 2017 (109) (remove)
Institute
- Fachbereich Medizintechnik und Technomathematik (45)
- INB - Institut für Nano- und Biotechnologien (24)
- IfB - Institut für Bioengineering (14)
- Fachbereich Chemie und Biotechnologie (11)
- Fachbereich Maschinenbau und Mechatronik (11)
- Fachbereich Wirtschaftswissenschaften (10)
- Fachbereich Bauingenieurwesen (9)
- Fachbereich Luft- und Raumfahrttechnik (9)
- Fachbereich Elektrotechnik und Informationstechnik (8)
- Fachbereich Energietechnik (7)
Has Fulltext
- no (109)
Document Type
- Article (109) (remove)
Keywords
- 3D nonlinear finite element model (1)
- CNOT (1)
- Capacitive field-effect (1)
- Chemical images (1)
- Chemical sensor (1)
- Dehydrogenase (1)
- Diaphorase (1)
- Dry-low-NOx (DLN) combustion (1)
- EIS capacitive sensor (1)
- Effective modal mass (1)
- Electrolyte–insulator–semiconductor (1)
- Enzymatic biosensor (1)
- Enzyme logic gate (1)
- High hydrogen combustion (1)
- Hotelling’s T² test (1)
- Hydrogen combustion (1)
- Hydrogen gas turbine (1)
- LAPS (1)
- Light-addressable potentiometric sensor (1)
- Micromix combustion (1)
- Natural frequency (1)
- Negative impedance convertor (1)
- O2 plasma (1)
- Resonance-mode measurement (1)
- Simultaneous determination (1)
- Suspension bridge (1)
- Thin shell finite elements (1)
- XOR (1)
- annealing (1)
- change management (1)
- churches (1)
- complete block symmetry (1)
- diversity management (1)
- earthquake engineering (1)
- electrolyte-insulator semiconductor sensor (EIS) (1)
- engineering (1)
- equivalent stiffness (1)
- granular silo (1)
- hydroxylation (1)
- hypoplasticity (1)
- innovation management (1)
- likelihood ratio test (1)
- macro-element (1)
- nonlinear transient analyses (1)
- research association (1)
- surface functionalization (1)
- truss (1)
- uniformly most powerful invariant test (1)
- vault (1)
Is part of the Bibliography
- no (109)
In this paper, carbon nanotubes (CNTs) were incorporated in penicillinase-phospholipid Langmuir and Langmuir–Blodgett (LB) films to enhance the enzyme catalytic properties. Adsorption of the penicillinase and CNTs at dimyristoylphosphatidic acid (DMPA) monolayers at the air–water interface was investigated by surface pressure–area isotherms, vibrational spectroscopy, and Brewster angle microscopy. The floating monolayers were transferred to solid supports through the LB technique, forming mixed DMPA-CNTs-PEN films, which were investigated by quartz crystal microbalance, vibrational spectroscopy, and atomic force microscopy. Enzyme activity was studied with UV–vis spectroscopy and the feasibility of the supramolecular device nanostructured as ultrathin films were essayed in a capacitive electrolyte–insulator–semiconductor (EIS) sensor device. The presence of CNTs in the enzyme–lipid LB film not only tuned the catalytic activity of penicillinase but also helped conserve its enzyme activity after weeks, showing increased values of activity. Viability as penicillin sensor was demonstrated with capacitance/voltage and constant capacitance measurements, exhibiting regular and distinctive output signals over all concentrations used in this work. These results may be related not only to the nanostructured system provided by the film, but also to the synergism between the compounds on the active layer, leading to a surface morphology that allowed a fast analyte diffusion because of an adequate molecular accommodation, which also preserved the penicillinase activity. This work therefore demonstrates the feasibility of employing LB films composed of lipids, CNTs, and enzymes as EIS devices for biosensing applications.
Für Auftragschweißaufgaben existiert eine Vielzahl an verfahrenstechnischen
Prozessvarianten, die je nach Charakteristik und Anwendungsfall
ausgewählt werden. Ein Nachteil der vorwiegend verwendeten Metall-
Schutzgasschweißprozesse (MSG) für das Auftragschweißen ist durch die
direkte Kopplung von Drahtvorschub zu Energieeintrag gegeben. Die vorgestellte
Zweidraht-Prozessvariante kann durch die Ausbildung eines übertragenen
und eines nicht-übertragenen Lichtbogens die elektrische Leistung
beider Lichtbögen variieren und damit einen direkten Einfluss auf
die Prozessgrößen Abschmelzleistung und Aufschmelzgrad nehmen. Im
Speziellen besteht über die Entkopplung von Drahtvorschub zu Schweißstromstärke
die Möglichkeit eines niederenergetischen Betriebs trotz hoher
Drahtvorschubgeschwindigkeit. Damit lassen sich Aufschmelzgrade
unter 2% umsetzen und Abschmelzleistungen bis zu 15 kg/h realisieren.
Silos generally work as storage structures between supply and demand for various goods, and their structural safety has long been of interest to the civil engineering profession. This is especially true for dynamically loaded silos, e.g., in case of seismic excitation. Particularly thin-walled cylindrical silos are highly vulnerable to seismic induced pressures, which can cause critical buckling phenomena of the silo shell. The analysis of silos can be carried out in two different ways. In the first, the seismic loading is modeled through statically equivalent loads acting on the shell. Alternatively, a time history analysis might be carried out, in which nonlinear phenomena due to the filling as well as the interaction between the shell and the granular material are taken into account. The paper presents a comparison of these approaches. The model used for the nonlinear time history analysis considers the granular material by means of the intergranular strain approach for hypoplasticity theory. The interaction effects between the granular material and the shell is represented by contact elements. Additionally, soil–structure interaction effects are taken into account.
An enzyme-based reversible Controlled NOT (CNOT) logic gate operating on a semiconductor transducer
(2017)
An enzyme-based biocatalytic system mimicking operation of a logically reversible Controlled NOT (CNOT) gate has been interfaced with semiconductor electronic transducers. Electrolyte–insulator–semiconductor (EIS) structures have been used to transduce chemical changes produced by the enzyme system to an electronically readable capacitive output signal using field-effect features of the EIS device. Two enzymes, urease and esterase, were immobilized on the insulating interface of EIS structure producing local pH changes performing XOR logic operation controlled by various combinations of the input signals represented by urea and ethyl butyrate. Another EIS transducer was functionalized with esterase only, thus performing Identity (ID) logic operation for the ethyl butyrate input. Both semiconductor devices assembled in parallel operated as a logically reversible CNOT gate. The present system, despite its simplicity, demonstrated for the first time logically reversible function of the enzyme system transduced electronically with the semiconductor devices. The biomolecular realization of a CNOT gate interfaced with semiconductors is promising for integration into complex biomolecular networks and future biosensor/biomedical applications.